please post your query to get data, in general to get the data in order use order by in your query.

If you want your four option in single column in order by QuestionId and Option then try this query

SELECT  Qno,Options,OptionValues
FROM
(
SELECT questionNo AS QNo,Option1 AS [1],Option2 AS [2],Option3 AS [3],Option4 AS [4]
FROM Quiz)P
UNPIVOT
(OptionValues FOR Options IN ([1], [2], [3], [4])
) AS Unpvt
order BY Qno,Options

OR

SELECT * FROM (
SELECT questionNo,1 AS OptNo,Option1 AS Options FROM Quiz
UNION ALL 
SELECT questionNo,2 AS OptNo,Option2 FROM Quiz
UNION ALL 
SELECT questionNo,3 AS OptNo,Option3 FROM Quiz
UNION ALL 
SELECT questionNo,4 AS OptNo,Option4 FROM Quiz
)AS tmp
ORDER BY questionNo,OptNo